Calculatorism

Isothermal Process Calculator

Enter initial pressure/volume and final volume to compute the work, heat and internal-energy change of an ideal-gas isothermal process.

Input Data

Initial Pressure Pa
Pa
Initial Volume M3
m³
Final Volume M3
m³
Moles Mol
mol
Temperature K
K

Results

Final pressure (Pa).
50,662.5Pa
Work done (J).
1,728.943896J
Heat transferred (J).
1,728.943896J
Internal energy change (J).
0J

At a glance:An isothermal process keeps temperature constant. For an ideal gas, P·V = n·R·T = const (Boyle's law), so when volume changes from V1 to V2 the pressure becomes P2 = P1·V1/V2. The work done by the gas is W = ∫P dV = n·R·T·ln(V2/V1) = P1·V1·ln(V2/V1). Because ideal-gas internal energy depends only on T, ΔU = 0, so by the first law ΔU = Q − W the heat transferred equals the work: Q = W (heat flows in during expansion, out during compression). This tool computes P2, W, Q and ΔU from P1, V1, V2 and (n, T for the work formula).

Formula

Boyle: P1·V1 = P2·V2

Work: W = n·R·T·ln(V2/V1) = P1·V1·ln(V2/V1)

ΔU = 0, Q = W

$$P_1 V_1 = P_2 V_2, \quad W = nRT \ln\frac{V_2}{V_1}, \quad \Delta U = 0, \quad Q = W$$

How to Use

  1. Enter initial pressure P1 and volume V1, final volume V2.
  2. Enter n and T to evaluate the work.
  3. The calculator returns P2, W, Q and ΔU.

Case Studies

Slow expansion

P1V1 = 1000 J equivalent, V2/V1 = 2, nT gives W = P1V1·ln2 ≈ 693 J.

Heat in = 693 J, ΔU = 0.

Typical Carnot isothermal branch.

FAQ

Why is ΔU zero in an isothermal ideal gas?

Internal energy of an ideal gas depends only on temperature; if T is constant, U is constant, so ΔU = 0 and all the heat added becomes work (or all work done on it is rejected as heat).

Work is positive for expansion?

By the convention W = work done by the gas, expansion (V2>V1) gives W>0 (gas does work, absorbs heat); compression gives W<0 (work done on gas, heat leaves).

Related Tools

References

Content review: Calculatorism Science Team. Results are for reference only; please refer to the relevant authorities for the official figures.

Found a problem with the results?

If this calculator's result is wrong, or you have any question about the calculation logic, please let us know. You are viewing:Isothermal Process Calculator(/physics/isothermal-process)。