Calculatorism

Arrhenius Equation Calculator

Enter the pre-exponential factor A, activation energy Ea, and absolute temperature T to compute the reaction rate constant k = A·e^(−Ea/RT).

Input Data

Pre Exponential
/s
Activation Energy
J/mol
Temperature
K

Results

0.71321945/s

At a glance:Enter the pre-exponential factor A, activation energy Ea, and absolute temperature T to compute the reaction rate constant k = A·e^(−Ea/RT).

Formula

k = A · e^(−Ea / (R·T)), R = 8.314 J/(mol·K).

$$k = A\,e^{-E_a/(RT)}$$
$$\ln k = \ln A - \dfrac{E_a}{R T}$$

How to Use

  1. Enter the pre-exponential factor A and activation energy Ea (J/mol).
  2. Enter the absolute temperature T in kelvin.
  3. The calculator returns the rate constant k.

FAQ

Must temperature be in kelvin (K)?

Yes, you must use the absolute temperature in kelvin. The Arrhenius exponent is −Ea/(RT), where T is the thermodynamic absolute temperature. Using °C gives wrong results; convert first: T(K) = T(°C) + 273.15, e.g. 25°C = 298.15 K.

Should activation energy be J/mol or kJ/mol?

It must match the unit of the gas constant R. This calculator uses R = 8.314 J/(mol·K), so enter Ea in J/mol. If your source gives kJ/mol, multiply by 1000 first (e.g. 75 kJ/mol = 75000 J/mol); otherwise the exponent is 1000× too small and the result is severely wrong.

Why does a small temperature rise speed up the reaction a lot?

Because k depends on temperature exponentially as e^(−Ea/RT). A slight rise sharply increases the fraction of molecules whose energy exceeds the activation barrier (the tail of the Boltzmann distribution). Empirically, a ~10°C rise roughly doubles to triples many reaction rates.

How do I find activation energy Ea from experiments?

Take logs: ln k = ln A − Ea/(R·T). Measure k at several temperatures and plot ln k against 1/T; you get a straight line whose slope = −Ea/R, so Ea = −slope × R, and the intercept = ln A gives the pre-exponential factor. This is the standard use of an Arrhenius plot.

What does the pre-exponential factor A represent?

A (pre-exponential factor) summarizes the total collision frequency and whether the collision orientation is correct; think of it as the 'rate ceiling if there were no energy barrier'. When Ea = 0 or T is extremely high so the exponent approaches 1, k approaches A. Its unit is the same as k and depends on the reaction order.

Related Tools

References

Content review: Calculatorism Science Team. Results are for reference only; please refer to the relevant authorities for the official figures.

Found a problem with the results?

If this calculator's result is wrong, or you have any question about the calculation logic, please let us know. You are viewing:Arrhenius Equation Calculator(/chemistry/arrhenius)。